Whether you decide to fly into Rome or Florence, the journey into Bucine, Tuscany is fairly simple. Below are links to the Italian train’s timetables and ticket purchase portal and driving directions.
The train trip from Rome Termini Station to Bucine is about 3 hours
The driving time is 2 – 3 hours
The train trip from Florence to Bucine is about 45 minutes
The driving time is about 1 hour